The Trifluoromethyl Anion

First evidence for the existence of free trifluoromethyl anion CF₃^? has been obtained. The 3D‐caged potassium cation in [K(crypt‐222)]⁺ is inaccessible to CF₃^?, thus rendering it uncoordinated (“naked”). Ionic [K(crypt‐222)]⁺ CF₃^? has been characterized by single‐crystal X‐ray diffraction, solution NMR spectroscopy, DFT calculations, and reactivity toward electrophiles.     

On weak* convergent sequences in duals of symmetric spaces of <Emphasis Type="Italic">τ</Emphasis>-measurable operators

It is shown that the pre-dual of a σ-finite von Neumann algebra has property (k) in the sense of Figiel, Johnson and Pelczyński [12]. This resolves in the affirmative an open question raised in [12]. It is shown further that a weakly sequentially complete symmetric space E of τ-measurable operators affiliated with a semifinite σ-finite von Neumann algebra has property (k).     

Homogeneous nucleophilic radiofluorination and fluorination with phosphazene hydrofluorides

A series of phosphazenium hydrofluorides, P(1)(tBu)·[(18/19)F]HF, P(1)(tOct)·[(18/19)F]HF, P(2)(Et)·[(18/19)F]HF, and P(4)(tBu)·[(18/19)F]HF, was synthesized. The radioactive phosphazenium [(18)F]hydrofluorides were obtained by the one-step formation and trapping of gaseous [(18)F]HF with the respective phosphazene bases. The [(19)F] isotopomers were prepared from the corresponding phosphazene bases and Et(3)N·3HF. Under the design of experiment (DoE)-optimized conditions, P(2)(Et)·HF and P(4)(tBu)·HF fluorinated alkyl chlorides, bromides, and pseudohalides in 76-98% yield, but gave lower yields with iodides and electron-deficient arenes. DoE models showed that fluorination can be performed in glass vessels, and that the reactivity of P(2)(Et)·HF and P(4)(tBu)·HF is dominated by solvent polarity but is insensitive to water to at least 2 equiv. In contrast, P(1)(tBu)·HF and P(1)(tOct)·HF were unstable towards autofluorolysis. DFT calculations were performed to rationalize this finding in terms of diminished steric bulk, higher Parr's electrophilicity, and chemical hardness of P(1)(R)H(+). The corresponding radiofluorination reaction gave no valid DoE model but displayed similar substrate scope. High specific activity and excellent radiochemical yields with various pseudohalides (81-91%) suggest that the proposed radiofluorination methodology can complement the current [(18)F]KF/Kryptofix methods, particularly in the areas for which nonpolar reaction conditions are required.     

Peculiarities of the complexation of copper and silver adducts of a 3,5-bis(trifluoromethyl)pyrazolate ligand with organoiron compounds

Interaction of the copper, {[3,5-(CF(3))(2)Pz]Cu}(3), and silver, {[3,5-(CF(3))(2)Pz]Ag}(3), macrocycles [3,5-(CF(3))(2)Pz = 3,5-bis(trifluoromethyl)pyrazolate] with cyclooctatetraeneiron tricarbonyl, (cot)Fe(CO)(3), was investigated by IR and NMR spectroscopy for the first time. The formation of 1:1 complexes was observed at low temperatures in hexane. The composition of the complexes (1:1) and their thermodynamic characteristics in hexane and dichloromethane were determined. The π-electron system of (cot)Fe(CO)(3) was proven to be the sole site of coordination in solution and in the solid state. However, according to the single-crystal X-ray data, the complex has a different (2:1) composition featuring the sandwich structure. The complexes of ferrocene with copper and silver macrocycles have a columnar structure (X-ray data).     

Functions of normal operators under perturbations

In Peller (1980) [27], Peller (1985) [28], Aleksandrov and Peller (2009) [2], Aleksandrov and Peller (2010) [3], and Aleksandrov and Peller (2010) [4] sharp estimates for f(A)−f(B) were obtained for self-adjoint operators A and B and for various classes of functions f on the real line R. In this paper we extend those results to the case of functions of normal operators. We show that if a function f belongs to the Hölder class Λα(R²), 0<α<1, of functions of two variables, and N₁ and N₂ are normal operators, then ‖f(N₁)−f(N₂)‖?const‖fΛα_‖‖N₁−N₂α^‖. We obtain a more general result for functions in the space for an arbitrary modulus of continuity ω. We prove that if f belongs to the Besov class , then it is operator Lipschitz, i.e., . We also study properties of f(N₁)−f(N₂) in the case when f∈Λα(R²) and N₁−N₂ belongs to the Schatten–von Neumann class Sp.     

Symmetric quasi-norms of sums of independent random variables in symmetric function spaces with the Kruglov property

Let X be a symmetric Banach function space on [0, 1] and let E be a symmetric (quasi)-Banach sequence space. Let f = {f _k } _k=1 ⁿ , n ≥ 1 be an arbitrary sequence of independent random variables in X and let {e _k } _k=1 ^∞ ? E be the standard unit vector sequence in E. This paper presents a deterministic characterization of the quantity

$||||\sum\limits_{k = 1}^n {{f_k}{e_k}|{|_E}|{|_X}} $

in terms of the sum of disjoint copies of individual terms of f. We acknowledge key contributions by previous authors in detail in the introduction, however our approach is based on the important recent advances in the study of the Kruglov property of symmetric spaces made earlier by the authors. Authors acknowledge support from the ARC.

     

Symmetric Functionals and Singular Traces

We study the construction and properties of positive linear functionals on symmetric spaces of measurable functions which are monotone with respect to submajorization. The construction of such functionals may be lifted to yield the existence of singular traces on certain non-commutative Marcinkiewicz spaces which generalize the notion of Dixmier trace.     

Form factors,deformed Knizhnik-Zamolodchikov equations and finite-gap integration

We study the limit of asymptotically free massive integrable models in which the algebra of nonlocal charges turns into affine algebra. The form factors of fields in that limit are described by KZ equations on level 0. We show the limit to be connected with finite-gap integration of classical integrable equations.     

Magnetic measurement of transport AC losses in Bi-2223/Ag tapes

Magnetic nature of the losses in superconducting wire carrying AC current implies that it should be possible to determine these losses in a contactless way. Ribbon-like samples are quite favorable for such an experiment, because a notable portion of magnetic flux related to losses ‘escapes' the sample volume and can be detected by an appropriate pick-up coil. In this case, a model describing the AC current penetration into the tape, based, e.g., on the critical state model, allows one to derive the losses from the pick-up coil signal. Because this signal is proportional to the number of coil turns, extension of the accessible range of measured voltages (and losses) can be achieved. We demonstrate the data obtained on a 1 cm long portion of a low-loss multifilamentary tape carrying AC current with frequency 35 Hz. The pick-up coil technique allowed us to reach loss level more than one order below the experimental limit for direct measurements.